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- W2153544498 abstract "Abstract The reaction of Ln(NO 3 ) 3 ·aq with K 3 [Fe(CN) 6 ] or K 3 [Co(CN) 6 ] and 2,2′:6′,2″‐terpyridine in water/methanol solution led to three one‐dimensional complexes: trans ‐[Ln(H 2 O) 4 (terpy)(μ‐CN) 2 M(CN) 4 ] n (Ln = La 3+ or Sm 3+ ; M = Fe 3+ or Co 3+ ). The structures of [SmFe] n ( 1 ), [SmCo] n ( 2 ) and [LaFe] n ( 3 ) have been solved; the complexes 1 and 2 crystallize in the monoclinic space P 2 1 / c and are isomorphous, complex 3 crystallizes in the triclinic space P $bar {1}$ . No significant magnetic interaction was found between the samarium( III ) and the iron( III ) ions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
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- W2153544498 date "2006-04-20" @default.
- W2153544498 modified "2023-10-18" @default.
- W2153544498 title "One Dimensional 3d–4f Heterometallic Compounds: Synthesis, Structure and Magnetic Properties" @default.
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- W2153544498 doi "https://doi.org/10.1002/ejic.200500999" @default.
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