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- W2153553769 abstract "Magnesium and zinc ion-mediated cycloaddition reactions of a carbonyl-conjugated nitrone, (Z)-N-(benzoylmethylene)aniline N-oxide to the allylic alcohols bearing a chirality at α-position give isoxazolidine-5-alcohol and isoxazolidine-4-alcohol derivatives, respectively, both in highly lk-1,2-inductive manners. α,α-Disubstitution of allylic alcohol dipolarophiles virtually inhibits the zinc ion-catalyzed reaction paths, and use of a coordinating solvent in the magnesium ion-catalyzed reactions leads to the reversal of regioselectivity. Reaction mechanism for the metal ion-catalyzed competitive cycloadditions is proposed." @default.
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- W2153553769 date "1995-07-01" @default.
- W2153553769 modified "2023-09-27" @default.
- W2153553769 title "Metal ion-mediated diastereoface-selective nitrone cycloadditions. Reaction mechanism for the reversal of regloselectivity observed in the magnesium and zinc ion-mediated nitrone cycloadditions of allylic alcohols" @default.
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- W2153553769 doi "https://doi.org/10.1016/0040-4039(95)00911-u" @default.
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