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• W2153586419 abstract "The selective dissolution of cobalt and the consequent surface enrichment of platinum in Pt­Co binary alloys immersed in 0.5mmol·m13 H2SO4 at 298K were investigated. Four different Pt­Co alloy thin films with various Pt contents, deposited on glassy carbon sheets by physical vapor deposition, were investigated: 51 at% Pt (Pt51­Co49), 43 at% Pt (Pt43­Co57), 28 at% Pt (Pt28­Co72), and 24 at% Pt (Pt24­Co76). When the thin films were immersed for 24 h in a 0.5mmol·m13 H2SO4 solution, a Pt-enriched layer was formed on the surface of all the alloys due to Coselective dissolution. The enriched layer formed in the higher-Pt alloys (Pt51­Co49 and Pt43­Co57) significantly suppressed further dissolution, whereas the lower-Pt alloys (Pt28­Co72 and Pt24­Co76) exhibited more extensive selective dissolution and roughened surfaces. In this study, the selective dissolution and surface morphology of the Pt­Co alloys are discussed on the basis of these experimental results. [doi:10.2320/matertrans.M2014107]" @default.
• W2153586419 created "2016-06-24" @default.
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• W2153586419 date "2014-01-01" @default.
• W2153586419 modified "2023-09-28" @default.
• W2153586419 title "Selective Dissolution of Pt–Co Binary Alloys and Surface Enrichment of Platinum in Sulfuric Acid Solution" @default.
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• W2153586419 doi "https://doi.org/10.2320/matertrans.m2014107" @default.
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