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• W2153664109 abstract "An analysis is presented of the significance of stripping chronopotentiometric (SCP) stripping peak parameters (peak potential, Ep, and peak half-width, w1/2) for determination of metal ion speciation. This study focuses on depletive SCP (low stripping current, Iτ constant), and considers the change in Ep and w1/2 in the presence of complexing and/or adsorbing ligands at both a conventional mercury drop electrode (HMDE) and a micro mercury droplet. We show that at a microelectrode, or at sufficiently long deposition time at a HMDE, the changes in Ep and w1/2 can be related to metal speciation in the bulk solution. Unlike transient stripping voltammetric methods such as DP-SV, depletive SCP is applicable even in the presence of adsorption of ligand and induced metal ion adsorption." @default.
• W2153664109 created "2016-06-24" @default.
• W2153664109 creator A5035701290 @default.
• W2153664109 creator A5062716126 @default.
• W2153664109 date "2002-11-01" @default.
• W2153664109 modified "2023-10-18" @default.
• W2153664109 title "Significance of wave form parameters in stripping chronopotentiometric metal speciation analysis" @default.
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• W2153664109 doi "https://doi.org/10.1016/s0022-0728(02)01157-9" @default.
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