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• W2153670047 endingPage "1965" @default.
• W2153670047 startingPage "1957" @default.
• W2153670047 abstract "Complex stoichiometry/composition and degree of oligomerization (oligomeric supramolecular complex formation) of cucurbit[6]uril (CB[6]) with N-alkyl- and N,N'-dialkylpiperazine were investigated in aqueous solutions by means of isothermal titration calorimetry (ITC), ESI-MS, NMR and light scattering measurements. It was found that the complex stability and the degree of oligomerization increase with elongating the alkyl chain attached to the piperazine core. X-ray crystallographic studies revealed a clear correlation between the structure of CB[6]-alkylpiperazine crystals obtained from aqueous solutions and the molecular weight/properties of host-guest oligomers existed in the solution as supramolecular seeds of crystal formation." @default.
• W2153670047 created "2016-06-24" @default.
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• W2153670047 date "2009-02-02" @default.
• W2153670047 modified "2023-10-01" @default.
• W2153670047 title "Supramolecular Complexation of<i>N</i>-Alkyl- and<i>N</i>,<i>N</i>′-Dialkylpiperazines with Cucurbit[6]uril in Aqueous Solution and in the Solid State" @default.
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• W2153670047 doi "https://doi.org/10.1002/chem.200800398" @default.
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