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- W2153757987 abstract "Die Photochemie der Titelverbindungen 1 entspricht der von α,β-ungesättigten Estern: Dekonjugation zu 2, β,δ-Cyclopropanbildung (→ 4) und [2 + 2]-Cycloaddition (→ 5, 7, 8) sowie substituierende Addition an Olefine (→ 9) Reaktionsmechanismus und präparative Aspekte werden diskutiert. Organic Lewis Acids, 331) The Photochemistry of Cyclic Acylals of Alkylidene-, Alkenylidene-, and Benzylidenemalonic Acids The photochemistry of the title compounds 1 resembles that of α,β-unsaturated esters. Observed reactions include deconjugation (→ 2), β, δ-cyclopropane ring closure(→ 4), and [2 + 2]-cycloaddition (→ 5, 7, 8) as well as ene-type addition to olefins (→ 9). Reaction mechanism and preparative aspects are discussed." @default.
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- W2153757987 date "1979-10-01" @default.
- W2153757987 modified "2023-10-03" @default.
- W2153757987 title "Zur Kenntnis organischer Lewis-Säuren, 331) Über die Photochemie cyclischer Acylale von Alkyliden-, Alkenyliden- und Benzylidenmalonsäuren" @default.
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- W2153757987 doi "https://doi.org/10.1002/cber.19791121002" @default.
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