FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2153821795> ?p ?o ?g. }

• W2153821795 endingPage "172" @default.
• W2153821795 startingPage "168" @default.
• W2153821795 abstract "The addition of 2-hydroxy-2-propyl radicals to n-butyl acrylate and n-butyl methacrylate has been investigated by time-resolved continuous wave electron paramagnetic resonance (TR CW EPR) and time-resolved Fourier transform electron paramagnetic resonance (TR FT EPR). The 2-hydroxy-2-propyl radicals were generated by the photolysis of acetone in propan-2-ol (through hydrogen abstraction) and by the photolysis of a ketone 5 (through α-cleavage). The TR CW and TR FT spectra were experimentally equivalent for the addition of 2-hydroxy-2-propyl radicals to n-butyl acrylate to produce 3a. However, there are distinct differences between the TR CW and TR FT spectra for the addition of 2-hydroxy-2-propyl radicals to n-butyl methacrylate which produces the radical adduct 4a. In particular, a number of hyperfine lines clearly present in the TR CW spectra are much weaker in, or are absent from, the TR FT spectra. The differences in the TR CW and TR FT spectra are attributed to hindered rotation, which is important in the spectrum of the adduct of 2-hydroxy-2-propyl radicals to n-butyl methacrylate (4a), but not in the spectrum of the adduct of 2-hydroxy-2-propyl radicals to n-butyl acrylate (3a). The hindered rotation is shown to selectively shorten the spin–spin relaxation time, T2, for certain hyperfine lines in the spectrum of 4a, resulting in broadening or disappearance of these lines and explaining the differences between the TR CW and TR FT spectra." @default.
• W2153821795 created "2016-06-24" @default.
• W2153821795 creator A5024297093 @default.
• W2153821795 creator A5041571379 @default.
• W2153821795 creator A5068787633 @default.
• W2153821795 date "2002-01-03" @default.
• W2153821795 modified "2023-10-16" @default.
• W2153821795 title "A comparative time-resolved CW EPR and FT EPR investigation of the addition of 2-hydroxy-2-propyl radicals to acrylate and methacrylate monomersDedicated to Professor Frank Wilkinson on the occasion of his retirement." @default.
• W2153821795 cites W1633193215 @default.
• W2153821795 cites W1966878965 @default.
• W2153821795 cites W1970467882 @default.
• W2153821795 cites W1970628717 @default.
• W2153821795 cites W1970733723 @default.
• W2153821795 cites W2010546574 @default.
• W2153821795 cites W2015120208 @default.
• W2153821795 cites W2019598478 @default.
• W2153821795 cites W2028674253 @default.
• W2153821795 cites W2033822501 @default.
• W2153821795 cites W2040885989 @default.
• W2153821795 cites W2040982242 @default.
• W2153821795 cites W2046187618 @default.
• W2153821795 cites W2051113658 @default.
• W2153821795 cites W2054913390 @default.
• W2153821795 cites W2060232185 @default.
• W2153821795 cites W2066319905 @default.
• W2153821795 cites W2076514060 @default.
• W2153821795 cites W2086347813 @default.
• W2153821795 cites W2096290853 @default.
• W2153821795 cites W2099511409 @default.
• W2153821795 cites W2101502577 @default.
• W2153821795 cites W2117250432 @default.
• W2153821795 cites W2147769806 @default.
• W2153821795 cites W2163135934 @default.
• W2153821795 cites W2171987013 @default.
• W2153821795 cites W2325283958 @default.
• W2153821795 cites W2604929926 @default.
• W2153821795 cites W2953040865 @default.
• W2153821795 doi "https://doi.org/10.1039/b107413j" @default.
• W2153821795 hasPublicationYear "2002" @default.
• W2153821795 type Work @default.
• W2153821795 sameAs 2153821795 @default.
• W2153821795 citedByCount "14" @default.
• W2153821795 countsByYear W21538217952012 @default.
• W2153821795 countsByYear W21538217952013 @default.
• W2153821795 countsByYear W21538217952014 @default.
• W2153821795 countsByYear W21538217952015 @default.
• W2153821795 countsByYear W21538217952016 @default.
• W2153821795 countsByYear W21538217952018 @default.
• W2153821795 countsByYear W21538217952021 @default.
• W2153821795 crossrefType "journal-article" @default.
• W2153821795 hasAuthorship W2153821795A5024297093 @default.
• W2153821795 hasAuthorship W2153821795A5041571379 @default.
• W2153821795 hasAuthorship W2153821795A5068787633 @default.
• W2153821795 hasConcept C108204754 @default.
• W2153821795 hasConcept C111998727 @default.
• W2153821795 hasConcept C121332964 @default.
• W2153821795 hasConcept C131538251 @default.
• W2153821795 hasConcept C139066938 @default.
• W2153821795 hasConcept C169912494 @default.
• W2153821795 hasConcept C178790620 @default.
• W2153821795 hasConcept C185592680 @default.
• W2153821795 hasConcept C187961010 @default.
• W2153821795 hasConcept C2777935641 @default.
• W2153821795 hasConcept C44228677 @default.
• W2153821795 hasConcept C46141821 @default.
• W2153821795 hasConcept C521977710 @default.
• W2153821795 hasConcept C54582936 @default.
• W2153821795 hasConcept C62520636 @default.
• W2153821795 hasConcept C75473681 @default.
• W2153821795 hasConcept C81022585 @default.
• W2153821795 hasConceptScore W2153821795C108204754 @default.
• W2153821795 hasConceptScore W2153821795C111998727 @default.
• W2153821795 hasConceptScore W2153821795C121332964 @default.
• W2153821795 hasConceptScore W2153821795C131538251 @default.
• W2153821795 hasConceptScore W2153821795C139066938 @default.
• W2153821795 hasConceptScore W2153821795C169912494 @default.
• W2153821795 hasConceptScore W2153821795C178790620 @default.
• W2153821795 hasConceptScore W2153821795C185592680 @default.
• W2153821795 hasConceptScore W2153821795C187961010 @default.
• W2153821795 hasConceptScore W2153821795C2777935641 @default.
• W2153821795 hasConceptScore W2153821795C44228677 @default.
• W2153821795 hasConceptScore W2153821795C46141821 @default.
• W2153821795 hasConceptScore W2153821795C521977710 @default.
• W2153821795 hasConceptScore W2153821795C54582936 @default.
• W2153821795 hasConceptScore W2153821795C62520636 @default.
• W2153821795 hasConceptScore W2153821795C75473681 @default.
• W2153821795 hasConceptScore W2153821795C81022585 @default.
• W2153821795 hasIssue "2" @default.
• W2153821795 hasLocation W21538217951 @default.
• W2153821795 hasOpenAccess W2153821795 @default.
• W2153821795 hasPrimaryLocation W21538217951 @default.
• W2153821795 hasRelatedWork W1450052830 @default.
• W2153821795 hasRelatedWork W1984704564 @default.
• W2153821795 hasRelatedWork W1989626061 @default.
• W2153821795 hasRelatedWork W1996893459 @default.
• W2153821795 hasRelatedWork W2035524773 @default.
• W2153821795 hasRelatedWork W2048245863 @default.
• W2153821795 hasRelatedWork W2079852184 @default.

• next