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- W2153901260 abstract "Abstract Nitroxyl‐iron(II) (HNO‐Fe II ) complexes are often unstable in aqueous solution, thus making them very difficult to study. Consequently, many fundamental chemical properties of Fe II ‐bound HNO have remained unknown. Using a comprehensive multinuclear ( 1 H, 15 N, 17 O) NMR approach, the acidity of the Fe II ‐bound HNO in [Fe(CN) 5 (HNO)] 3− was investigated and its p K a value was determined to be greater than 11. Additionally, HNO undergoes rapid hydrogen exchange with water in aqueous solution and this exchange process is catalyzed by both acid and base. The hydrogen exchange dynamics for the Fe II ‐bound HNO have been characterized and the obtained benchmark values, when combined with the literature data on proteins, reveal that the rate of hydrogen exchange for the Fe II ‐bound HNO in the interior of globin proteins is reduced by a factor of 10 6 ." @default.
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- W2153901260 date "2014-09-09" @default.
- W2153901260 modified "2023-10-18" @default.
- W2153901260 title "Acidity and Hydrogen Exchange Dynamics of Iron(II)-Bound Nitroxyl in Aqueous Solution" @default.
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- W2153901260 doi "https://doi.org/10.1002/anie.201407018" @default.
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