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• W2154122246 abstract "A two-step synthesis of structurally diverse pyrrole-containing bicyclic systems is reported. ortho-Nitro-haloarenes coupled with vinylic N-methyliminodiacetic acid (MIDA) boronates generate ortho-vinyl-nitroarenes, which undergo a “metal-free” nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide substrate tolerance and it is applicable in the preparation of more complex “drug-like” molecules. Interestingly, an ortho-nitro-allylarene derivative furnished a cyclic β-aminophosphonate motif." @default.
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• W2154122246 date "2015-03-25" @default.
• W2154122246 modified "2023-10-14" @default.
• W2154122246 title "Vinylic MIDA Boronates: New Building Blocks for the Synthesis of Aza-Heterocycles" @default.
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• W2154122246 doi "https://doi.org/10.1002/chem.201406549" @default.
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