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- W2154131033 abstract "Abstract Br3CoN5C4H19, (I), crystallizes in the monoclinic system, space group C2/c, with cell constants a = 24.579(9),b = 8.665(3),c = 14.409(5) A, and β = 92.69(3)˚; V = 2988.87 A3 and d (MW = 435.875, Z = 8) = 2.097 gm cm−3. Data were collected in the range 4˚ ≤ 2θ ≤ 50˚, for a total of 2823 reflections, of which 1409 were independent and had I ≥ 3σ(I). The structure factors were corrected for absorption (μ = 90.882 cm−1) using psi scan curves obtained from reflections near X = 90˚. The transmission coefficients ranged from 0.68 to 0.99. The structure was solved by direct methods and refinement converged to final discrepancy indices of R(F) = 0.0601 and Rw(F) = 0.0663. The cobalt configuration and chelate ring conformations for (I) were found to be the preferred (lel)2-Δ(δδ) and Δ(λλ). The Co-N distances to the en rings are 1.961(6), 1.960(6), 1.977(6), 1951(6) A, while that to the -NH3 ligand is 1.963(6) A. The C-C distances are 1.52(1) and 1.50(1) A; finally, the Co-Br distance is 2.403(1) A." @default.
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- W2154131033 date "1993-01-01" @default.
- W2154131033 modified "2023-09-27" @default.
- W2154131033 title "THE PHENOMENON OF CONGLOMERATE CRYSTALLIZATION. XXV. SPONTANEOUS RESOLUTION IN COORDINATION COMPOUNDS. THE CRYSTAL STRUCTURE OF [cis-Co(en)<sub>2</sub>(NH<sub>3</sub>)Br]Br<sub>2</sub>" @default.
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- W2154131033 doi "https://doi.org/10.1080/00958979308035147" @default.
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