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- W2154186246 abstract "Abstract The enthalpy of Li 4 SiO 4 was obtained between 363 and 1300 K using isothermal drop calorimetry. Anisothermal calorimetry was used for the identification of two second-order transitions and the measurement of the enthalpy of fusion. The smoothed enthalpy between 298 and 1300 K results in H °( T ) − H °(298) − 17156 + 73.694 T + 0.103210 T 2 − 4163115 T −1 J mol −1 . The heat capacity was derived by differentiation. The value extrapolated to 298 K is C p ,298 = 182.1 J K −1 mol −1 . The critical temperatures of the second-order transitions are T c1 = 938 K and T c2 = 996 K. The enthalpy of fusion is Δ fus H = 53 kJ mol −1 at the melting temperature T m = 1531 K. An isotope effect of the 6 Li enrichment on the melting temperature and enthalpy of fusion could not be discerned." @default.
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- W2154186246 date "1996-10-01" @default.
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- W2154186246 title "Enthalpy, heat capacity, second-order transitions and enthalpyof fusion of Li4SiO4 by high-temperature calorimetry" @default.
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- W2154186246 doi "https://doi.org/10.1016/s0040-6031(96)02996-6" @default.
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