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- W2154187029 endingPage "4421" @default.
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- W2154187029 abstract "Treatment of Tp′Rh(PMe3)Cl2 and Tp′Rh(CNCH2CMe3)Cl2 with Cp2ZrH2 produces Tp′Rh(PMe3)H2 and Tp′Rh(CNCH2CMe3)H2, respectively, in excellent yield. Photolysis of benzene solutions of each dihydride complex generates hydrogen and the fragment [Tp′Rh(L)] which inserts into the solvent C–H bond. The phosphine dihydride has also been shown to be a catalyst for the hydrogenation of biphenylene, showing a capability to cleave C–C bonds. Reductive elimination of benzene from Tp′Rh(PMe3)PhH is nearly 250 times slower than from Cp*Rh(PMe3)PhH." @default.
- W2154187029 created "2016-06-24" @default.
- W2154187029 creator A5026982239 @default.
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- W2154187029 date "2009-09-01" @default.
- W2154187029 modified "2023-09-23" @default.
- W2154187029 title "Synthesis, characterization, and C–H/C–C cleavage reactions of two rhodium–trispyrazolylborate dihydrides" @default.
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- W2154187029 doi "https://doi.org/10.1016/j.ica.2009.03.022" @default.
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