Matches in SemOpenAlex for { <https://semopenalex.org/work/W2154203493> ?p ?o ?g. }
- W2154203493 endingPage "10155" @default.
- W2154203493 startingPage "10155" @default.
- W2154203493 abstract "Gas-phase ion–molecule reactions, complemented by DFT and wave-function based electronic structure calculations, are presented, which permit rather detailed descriptions of two fundamental processes related to the activation of methane at room temperature. (i) Recent examples are discussed, which shed light on the role of oxygen-centered radicals in the first step of the oxidative dimerization of methane, i.e. the homolytic C–H bond cleavage of methane. (ii) Thermal ligand exchange processes of the type ML+ + CH4→ M(CH3)+ + LH are analyzed in detail with an emphasis on L = H and F attached to various transition-metal cations M+. It will be demonstrated inter alia that similar systems, e.g. MH+ (M = Ni, Pd, Pt) in their room-temperature reactions with methane, actually exhibit fundamentally different mechanistic scenarios." @default.
- W2154203493 created "2016-06-24" @default.
- W2154203493 creator A5059088310 @default.
- W2154203493 creator A5067992887 @default.
- W2154203493 date "2009-01-01" @default.
- W2154203493 modified "2023-10-03" @default.
- W2154203493 title "Ligand and electronic-structure effects in metal-mediated gas-phase activation of methane: A cold approach to a hot problem" @default.
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