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• W2154213389 abstract "Peculiarities of chemical reactions inside polymer globules with sizes falling in the nanometric range have been theoretically studied. The simplest example of a polymer-catalyzed bimolecular reaction between two low-molecular-weight compounds has been considered to illustrate the advantages of conducting chemical transformations in globular solution of macromolecules. Under theoretical examination of polymer-analogous transformations of polymer molecules, the possibility has been shown of reaction-induced conformational transitions between their coil and globular states. Besides, a pronounced effect has been revealed of the preferential sorption of low-molecular-weight reagents on composition of copolymers formed." @default.
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• W2154213389 date "2008-02-28" @default.
• W2154213389 modified "2023-09-23" @default.
• W2154213389 title "Polymer Globule as a Nanoreactor" @default.
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• W2154213389 doi "https://doi.org/10.1021/ma702710s" @default.
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