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• W2154367493 abstract "Abstract Ion‐like ethylzinc(II) compounds with weakly coordinating aluminates [Al(OR F ) 4 ] − and [(R F O) 3 Al‐F‐Al(OR F ) 3 ] − (R F =C(CF 3 ) 3 ) were synthesized in a one‐pot reaction and fully characterized by single‐crystal X‐ray diffraction, NMR and vibrational spectroscopy, and by quantum chemical calculations. The catalytic activity of ion‐like Et‐Zn[Al(OR F ) 4 ] in intermolecular hydroamination and in the unusual double hydroamination of anilines and alkynes was investigated. Favorable performance was also found in comparison to the Et 2 Zn/ [PhNMe 2 H] + [B(C 6 F 5 ) 4 ] − system generated in situ at lower catalyst loadings of 2.5 mol %." @default.
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• W2154367493 date "2015-08-11" @default.
• W2154367493 modified "2023-10-18" @default.
• W2154367493 title "Ethyl-Zinc(II)-Cation Equivalents: Synthesis and Hydroamination Catalysis" @default.
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• W2154367493 doi "https://doi.org/10.1002/chem.201502328" @default.
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