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- W2154400818 abstract "Abstract The infrared spectrum of kegelite has been measured and is discussed. The infrared spectra of 1 : 1 molar mixtures of leadhillite with pyrophyllite or with muscovite resemble the spectrum of kegelite, the chemical formula of which is a 1 : 1 stoichiometric sum of those of pyrophyllite and of the leadhillite polymorphs. Kegelite is not a physical mixture of these species, but its structure may be an interlayering of phyllosilicate and leadhillite-like structures within the unit cell. The unit cell parameters of pyrophyllite-1 Tc and the leadhillite polymorphs are compatible with each other and can be combined to give a cell with parameters close to those of the kegelite cell. A structural model for kegelite on these bases is suggested, which is also consistent with its thermal analysis. The formula of kegelite can be written as Pb 8 (SO 4 ) 2 (CO 3 ) 4 (OH) 4 (AlOH) 4 (Si 4 O 10 ) 2 ." @default.
- W2154400818 created "2016-06-24" @default.
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- W2154400818 date "1991-03-01" @default.
- W2154400818 modified "2023-09-25" @default.
- W2154400818 title "Kegelite: infrared spectroscopy and a structural hypothesis" @default.
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- W2154400818 doi "https://doi.org/10.1180/minmag.1991.055.378.11" @default.
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