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- W2154571586 abstract "Abstract The formation mechanism of copper(II) carbodiimide in aqueous ammonia solution was studied by synthetic and crystallographic means. The reduction of the starting Cu II solution led to the synthesis of solid Cu I intermediates, and the crystal structures of the two new compounds Cu(NCNH 2 )Cl ( a = 8.2925(4), b = 3.7275(1), c = 12.4534(4) Å, Pnma ) and the isostructural Cu(NCNH 2 )Br ( a = 8.406(3), b = 3.9229(9), c = 12.656(3) Å, Pnma ) were elucidated. A further increase in pH value by adding more ammonia led to the crystallization of two additional Cu I intermediates, Cu 2 NCN and the ammine adduct Cu 4 (NCN) 2 NH 3 . The former can be also made by the thermal decomposition of the latter whereas mild oxidation of Cu 4 (NCN) 2 NH 3 led to the formation of perfectly crystalline CuNCN." @default.
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- W2154571586 date "2009-12-22" @default.
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- W2154571586 title "An Investigation of the Formation Mechanism of Copper(II) Carbodiimide" @default.
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