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• W2154652502 abstract "Abstract This article discusses a number of reactions of potential synthetic interest occurring through photochemically generated organic radicals. Emphasis is placed on the nature of the resulting photoproducts, whose formation is discussed on a mechanistic basis. If available, experimental evidence (obtained by laser flash photolysis or related time‐resolved techniques) is provided. The material is organized according to the reaction types, for instance, homolytic cleavage, mesolytic cleavage, radical addition, and oxidative or reductive electron transfer. In addition to the classical carboncarbon or carbonhydrogen bond breaking processes, such as the Norrish type I reaction, the hydrogen abstraction, and the photo‐Fries or the photo‐Claisen rearrangements, a number of carbonheteroatom and heteroatomheteroatom cleavage processes are also covered. At the end of the article, a short section is included that deals with the experimental techniques for the characterization of photochemically generated radicals." @default.
• W2154652502 created "2016-06-24" @default.
• W2154652502 creator A5024328852 @default.
• W2154652502 creator A5087167831 @default.
• W2154652502 date "2012-01-13" @default.
• W2154652502 modified "2023-10-17" @default.
• W2154652502 title "Photo Induced Radical Reactions" @default.
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• W2154652502 doi "https://doi.org/10.1002/9781119953678.rad004" @default.
• W2154652502 hasPublicationYear "2012" @default.
• W2154652502 type Work @default.
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• W2154652502 hasAuthorship W2154652502A5024328852 @default.
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