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- W2154654325 abstract "The apparent molar volumes of glycine, L -alanine, and L -arginine in aqueous hydroxylamine sulfate solutions have been determined at<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M1><mml:mi>T</mml:mi><mml:mo>=</mml:mo><mml:mn>298.15</mml:mn></mml:math> K and atmospheric pressure. The standard partial molar volumes,<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M2><mml:mrow><mml:msubsup><mml:mrow><mml:mi>V</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow><mml:mrow><mml:mn>0</mml:mn></mml:mrow></mml:msubsup></mml:mrow></mml:math>, corresponding partial molar volumes of transfer,<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M3><mml:msub><mml:mrow><mml:mi mathvariant=normal>Δ</mml:mi></mml:mrow><mml:mrow><mml:mtext>t</mml:mtext><mml:mtext>r</mml:mtext></mml:mrow></mml:msub><mml:msubsup><mml:mrow><mml:mi>V</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow><mml:mrow><mml:mn>0</mml:mn></mml:mrow></mml:msubsup></mml:math>, and hydration numbers,<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M4><mml:mrow><mml:msub><mml:mrow><mml:mi>N</mml:mi></mml:mrow><mml:mrow><mml:mtext>H</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:math>, have been calculated for these α -amino acids from the experimental data. The<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M5><mml:msub><mml:mrow><mml:mi mathvariant=normal>Δ</mml:mi></mml:mrow><mml:mrow><mml:mtext>t</mml:mtext><mml:mtext>r</mml:mtext></mml:mrow></mml:msub><mml:msubsup><mml:mrow><mml:mi>V</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow><mml:mrow><mml:mn>0</mml:mn></mml:mrow></mml:msubsup></mml:math>values are positive for glycine, L -alanine, and L -arginine and are all increased with the increase in the concentration of hydroxylamine ions. These parameters obtained from the volumetric data are interpreted in terms of various mixing effects between amino acids and hydroxylamine sulfate in aqueous solutions." @default.
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- W2154654325 date "2013-01-01" @default.
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- W2154654325 title "Effect of Hydroxylamine Sulfate on Volumetric Behavior of Glycine,L-Alanine, andL-Arginine in Aqueous Solution" @default.
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