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- W2154804775 abstract "Two mixed amido-azido tin(IV) species bearing either C,N-chelating or bulky amido ligands were prepared by the reaction of the corresponding stannylene (e.g., Sn[N(SiMe 3 ) 2 ] 2 (1) or (L CN ) 2 Sn (2, L CN = 2-(N,N-dimethylaminomethyl)phenyl)) with Me 3 SiN 3 . Both products of the oxidative addition, Sn[N(SiMe 3 ) 2 ] 3 N 3 (3) and (L CN ) 2 Sn[N(SiMe 3 ) 2 ]N 3 (5), respectively, were fully characterized by both multinuclear NMR spectroscopy and XRD analysis. Heating of a mixture of 2 and Me 3 SiN 3 up to 100 °C lead to the formation of a novel dimeric species (L CN ) 2 Sn(μ-NSiMe 3 ) 2 Sn(L CN ) 2 (4), where the two tin atoms are bridged by two NSiMe 3 ligands, thus forming a four-membered diazadistannacycle. DFT calculations were also carried out to support the proposed reaction mechanisms." @default.
- W2154804775 created "2016-06-24" @default.
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- W2154804775 date "2014-06-01" @default.
- W2154804775 modified "2023-10-18" @default.
- W2154804775 title "Comparison of reactivity of <i>C</i>,<i>N</i>-chelated and Lappert’s stannylenes with trimethylsilylazide" @default.
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- W2154804775 doi "https://doi.org/10.1139/cjc-2013-0500" @default.
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