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- W2154976324 abstract "The structure, oxygen stoichiometry, and chemical and thermal expansion of Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) between 873 and 1173 K and oxygen partial pressures of 1 × 10-3 to 1 atm were determined by in situ neutron diffraction. BSCF has a cubic perovskite structure, space group Pm3̄m, across the whole T−pO2 region investigated. The material is highly oxygen deficient with a maximum oxygen stoichiometry (3 − δ) of 2.339(12) at 873 K and a pO2 of 1 atm and a minimum of 2.192(15) at 1173 K and a pO2 of 10-3 atm. Good agreement is obtained between oxygen stoichiometry data determined by neutron diffraction and thermogravimetry. In the range covered by the experiments, the thermal and chemical expansion coefficients are 19.0(5)−20.8(6) × 10-6 K-1 and 0.016(2)−0.026(4), respectively." @default.
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- W2154976324 date "2006-03-18" @default.
- W2154976324 modified "2023-10-14" @default.
- W2154976324 title "Oxygen Stoichiometry and Chemical Expansion of Ba<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>0.8</sub>Fe<sub>0.2</sub>O<sub>3</sub><sub>-</sub><sub>δ</sub> Measured by in Situ Neutron Diffraction" @default.
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- W2154976324 doi "https://doi.org/10.1021/cm052763x" @default.
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