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- W2155016053 endingPage "4249" @default.
- W2155016053 startingPage "4246" @default.
- W2155016053 abstract "Abstract Fluoroalkylsulfonyl chlorides, R f SO 2 Cl, in which R f =CF 3 , C 4 F 9 , CF 2 H, CH 2 F, and CH 2 CF 3 , are used as a source of fluorinated radicals to add fluoroalkyl groups to electron‐deficient, unsaturated carbonyl compounds. Photochemical conditions, using Cu mediation, are used to produce the respective α‐chloro‐β‐fluoroalkylcarbonyl products in excellent yields through an atom transfer radical addition (ATRA) process. Facile nucleophilic replacement of the α‐chloro substituent is shown to lead to further diverse functionalization of the products." @default.
- W2155016053 created "2016-06-24" @default.
- W2155016053 creator A5063344415 @default.
- W2155016053 creator A5081853872 @default.
- W2155016053 date "2015-02-18" @default.
- W2155016053 modified "2023-10-18" @default.
- W2155016053 title "Efficient Cu-catalyzed Atom Transfer Radical Addition Reactions of Fluoroalkylsulfonyl Chlorides with Electron-deficient Alkenes Induced by Visible Light" @default.
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- W2155016053 doi "https://doi.org/10.1002/anie.201412199" @default.
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