FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2155115360> ?p ?o ?g. }

• W2155115360 endingPage "539" @default.
• W2155115360 startingPage "513" @default.
• W2155115360 abstract "When neutral molecules with low levels of vibrational excitation collide at metal surfaces, vibrational coupling to electron-hole pairs (EHPs) is not thought to be strong unless incidence energies are high. However, there is accumulating evidence that coupling of large-amplitude molecular vibration to metallic electron degrees of freedom can be much stronger even at the lowest accessible incidence energies. As reaching a chemical transition-state also involves large-amplitude vibrational motion, we pose the basic question: are electronically non-adiabatic couplings important at transition states of reactions at metal surfaces? We have indirect evidence in at least one example that the dynamics and rates of chemical reactions at metal surfaces may be strongly influenced by electronically non-adiabatic coupling. This implies that theoretical approaches relying on the Born–Oppenheimer approximation (BOA) may not accurately reflect the nature of transition-state traversal in reactions of catalytic importance. Developing a predictive understanding of surface reactivity beyond the BOA represents one of the most important challenges to current research in physical chemistry. This article reviews the experimental evidence and underlying theoretical framework concerning these and related topics." @default.
• W2155115360 created "2016-06-24" @default.
• W2155115360 creator A5008024853 @default.
• W2155115360 creator A5012956193 @default.
• W2155115360 creator A5021304343 @default.
• W2155115360 date "2004-10-01" @default.
• W2155115360 modified "2023-10-12" @default.
• W2155115360 title "Electronically non-adiabatic interactions of molecules at metal surfaces: Can we trust the Born–Oppenheimer approximation for surface chemistry?" @default.
• W2155115360 cites W1635304823 @default.
• W2155115360 cites W1658777500 @default.
• W2155115360 cites W1673158857 @default.
• W2155115360 cites W1964084126 @default.
• W2155115360 cites W1964137017 @default.
• W2155115360 cites W1965296404 @default.
• W2155115360 cites W1966534982 @default.
• W2155115360 cites W1968131121 @default.
• W2155115360 cites W1970705026 @default.
• W2155115360 cites W1977046005 @default.
• W2155115360 cites W1977149960 @default.
• W2155115360 cites W1977319062 @default.
• W2155115360 cites W1980117816 @default.
• W2155115360 cites W1983038459 @default.
• W2155115360 cites W1985299141 @default.
• W2155115360 cites W1985474014 @default.
• W2155115360 cites W1986095217 @default.
• W2155115360 cites W1987943952 @default.
• W2155115360 cites W1989787213 @default.
• W2155115360 cites W1990898561 @default.
• W2155115360 cites W1992840343 @default.
• W2155115360 cites W1996232161 @default.
• W2155115360 cites W1999236159 @default.
• W2155115360 cites W1999244887 @default.
• W2155115360 cites W2002724440 @default.
• W2155115360 cites W2003263523 @default.
• W2155115360 cites W2006634195 @default.
• W2155115360 cites W2008605750 @default.
• W2155115360 cites W2010124008 @default.
• W2155115360 cites W2013074928 @default.
• W2155115360 cites W2018478185 @default.
• W2155115360 cites W2019750243 @default.
• W2155115360 cites W2022584634 @default.
• W2155115360 cites W2027899995 @default.
• W2155115360 cites W2029637331 @default.
• W2155115360 cites W2031316117 @default.
• W2155115360 cites W2033989230 @default.
• W2155115360 cites W2034357934 @default.
• W2155115360 cites W2037499908 @default.
• W2155115360 cites W2037987234 @default.
• W2155115360 cites W2039767682 @default.
• W2155115360 cites W2041084020 @default.
• W2155115360 cites W2041282906 @default.
• W2155115360 cites W2041345164 @default.
• W2155115360 cites W2044888758 @default.
• W2155115360 cites W2046001409 @default.
• W2155115360 cites W2046141129 @default.
• W2155115360 cites W2051421015 @default.
• W2155115360 cites W2052032483 @default.
• W2155115360 cites W2053888525 @default.
• W2155115360 cites W2054428532 @default.
• W2155115360 cites W2056135312 @default.
• W2155115360 cites W2056335348 @default.
• W2155115360 cites W2057254948 @default.
• W2155115360 cites W2059011370 @default.
• W2155115360 cites W2060375341 @default.
• W2155115360 cites W2061295058 @default.
• W2155115360 cites W2062053290 @default.
• W2155115360 cites W2063337396 @default.
• W2155115360 cites W2072575260 @default.
• W2155115360 cites W2075268765 @default.
• W2155115360 cites W2077623636 @default.
• W2155115360 cites W2079608237 @default.
• W2155115360 cites W2079869991 @default.
• W2155115360 cites W2082432262 @default.
• W2155115360 cites W2085500318 @default.
• W2155115360 cites W2085608654 @default.
• W2155115360 cites W2086038518 @default.
• W2155115360 cites W2087302662 @default.
• W2155115360 cites W2090573034 @default.
• W2155115360 cites W2091058084 @default.
• W2155115360 cites W2094617455 @default.
• W2155115360 cites W2103278445 @default.
• W2155115360 cites W2147710981 @default.
• W2155115360 cites W2151752974 @default.
• W2155115360 cites W2154144173 @default.
• W2155115360 cites W2162884916 @default.
• W2155115360 cites W2164142691 @default.
• W2155115360 cites W2179416492 @default.
• W2155115360 cites W4232795036 @default.
• W2155115360 cites W4247955856 @default.
• W2155115360 doi "https://doi.org/10.1080/01442350500037521" @default.
• W2155115360 hasPublicationYear "2004" @default.
• W2155115360 type Work @default.
• W2155115360 sameAs 2155115360 @default.
• W2155115360 citedByCount "161" @default.
• W2155115360 countsByYear W21551153602012 @default.
• W2155115360 countsByYear W21551153602013 @default.
• W2155115360 countsByYear W21551153602014 @default.
• W2155115360 countsByYear W21551153602015 @default.

• next