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• W2155154051 startingPage "87" @default.
• W2155154051 abstract "High resolution infrared emission spectra of ZnH, ZnD, CdH, and CdD have been recorded with a Fourier transform spectrometer. The v =1 fi 0 and v =2 fi 1 bands of ZnH, ZnD, CdH, and CdD, as well as the v =3 fi 2 band of ZnD were observed for the X 2 R + ground electronic state. In addition, new rotational spectra have been recorded for CdH and CdD using a tunable far-infrared spectrometer, and pure rotational transitions in the v = 1 level of the ground state were measured. The new data were combined with the previous data from diode laser infrared spectra and pure rotation spectra of ZnH/ZnD and CdH/CdD available in the literature. The data from all isotopologues were fitted together using a Dunham-type energy level expression for 2 R + states, and Born–Oppenheimer breakdown correction parameters were obtained. The equilibrium rotational constants (Be )o f 64 ZnH, 64 ZnD, 114 CdH, and 114 CdD were determined to be 6.691332(17), 3.402156(7), 5.447074(18), and 2.750761(6) cm � 1 , respectively, and the associated equilibrium internuclear distances (re) are 1.593478(2), 1.593001(2), 1.760098(3), and 1.759695(2) A ˚ , respectively. Simple reduced mass scaling for the spin–rotation interaction constants of ZnH and CdH fully accounted for their isotopologue dependence, and no Born–Oppenheimer breakdown correction was required for these parameters." @default.
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• W2155154051 date "2006-05-01" @default.
• W2155154051 modified "2023-10-14" @default.
• W2155154051 title "Multi-isotopologue analyses of new vibration–rotation and pure rotation spectra of ZnH and CdH" @default.
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• W2155154051 doi "https://doi.org/10.1016/j.jms.2006.03.004" @default.
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