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- W2155201516 abstract "The structure of the hydrated and the dimethyl sulfoxide solvated rubidium ions in solution has been determined by means of large-angle X-ray scattering (LAXS) and extended X-ray absorption fine structure (EXAFS) studies. The models of the hydrated and dimethyl sulfoxide solvated rubidium ions fitting the experimental data best are square antiprisms with Rb−O bond distances of 2.98(2) and 2.98(3) Å, respectively. The EXAFS data show a significant asymmetry in the Rb−O bond distance distribution with C3 values of 0.0076 and 0.015 Å3, respectively. No second hydration sphere is observed around the hydrated rubidium ion. The dimethyl sulfoxide solvated rubidium ion displays a Rb−O−S bond angle of ca. 130°, which is typical for a medium hard electron acceptor such as rubidium." @default.
- W2155201516 created "2016-06-24" @default.
- W2155201516 creator A5002905256 @default.
- W2155201516 creator A5079120866 @default.
- W2155201516 date "2004-05-01" @default.
- W2155201516 modified "2023-10-02" @default.
- W2155201516 title "Structure of the Hydrated and Dimethyl Sulfoxide Solvated Rubidium Ions in Solution" @default.
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- W2155201516 doi "https://doi.org/10.1021/ic030310t" @default.
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