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- W2155207427 abstract "Condensation of N-tert-butanesulfinamide (S)-1 with trifluoroacetaldehyde hydrate 2a afforded 2-methyl-N-(2,2,2-trifluoroethylidene)propane-2-sulfinamide 3. Without isolation and purification, imine 3 was added to various aryllithium reagents to give highly diastereomerically enriched adducts 5a−g. Acidic methanolysis of 5a−g provided the desired 1-aryl-2,2,2-trifluoroethylamine hydrochloride compounds 6a−g." @default.
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- W2155207427 date "2007-01-26" @default.
- W2155207427 modified "2023-10-07" @default.
- W2155207427 title "Asymmetric Syntheses of 1-Aryl-2,2,2-trifluoroethylamines via Diastereoselective 1,2-Addition of Arylmetals to 2-Methyl-<i>N</i>-(2,2,2-trifluoroethylidene)propane-2-sulfinamide" @default.
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- W2155207427 doi "https://doi.org/10.1021/ol063001q" @default.
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