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- W2155226860 endingPage "4516" @default.
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- W2155226860 abstract "An asymmetric tail-to-tail cross-hydroalkenylation of vinylarenes with terminal olefins was achieved by catalysis with NiH complexes bearing chiral N-heterocyclic carbenes (NHCs). The reaction provides branched gem-disubstituted olefins with high enantioselectivity (up to 94 % ee) and chemoselectivity (cross/homo product ratio: up to 99:1). Electronic effects of the substituents on the vinylarenes and on the N-aryl groups of the NHC ligands, but not a π,π-stacking mechanism, assist the steric effect and influence the outcome of the cross-hydroalkenylation." @default.
- W2155226860 created "2016-06-24" @default.
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- W2155226860 date "2015-02-05" @default.
- W2155226860 modified "2023-10-17" @default.
- W2155226860 title "Catalytic Asymmetric Hydroalkenylation of Vinylarenes: Electronic Effects of Substrates and Chiral N-Heterocyclic Carbene Ligands" @default.
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- W2155226860 doi "https://doi.org/10.1002/anie.201411882" @default.
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