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- W2155232748 abstract "The opportunity to test a new equation for the computation of the lattice energy and at the same time examine a disparity in the literature data for the enthalpy of formation of the azide ion, ΔHθƒ(N3−) (g) was the motivation for this study. The results confirm our earlier calculation and show the new equation to be reliable. Thermodynamic data produced in the study take values: ΔHθƒ(N3−)(g) = 144kJ mor−1ΔHθhyd(N3−) = −315 KJ mol−1 or ΔHθhyd(N3−) = −295 KJ mol−1UPOT(NaN3) = 732 kJ mol−1UPOT(KN3) = 659 kJ mol−1UPOT(RbN3) = 637 kJ mol−1UPOT(CsN3) = 612 kJ mol−1UPOT(TIN3) = 689 kJ mol−1. The lattice energies of azides whose enthalpies of formation are documented have been calculated as well as the enthalpy of formation of the azide radical." @default.
- W2155232748 created "2016-06-24" @default.
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- W2155232748 date "1977-01-01" @default.
- W2155232748 modified "2023-10-18" @default.
- W2155232748 title "Thermochemistry of azide salts and the azide ion using direct minimisation equations to obtain the lattice energy of the univalent azide salts" @default.
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- W2155232748 doi "https://doi.org/10.1016/0022-3697(77)90222-0" @default.
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