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- W2155309451 abstract "Metalla-cycloaddition: An unprecedented formal [4+2] cycloaddition reaction takes place when osmium hydrido alkenylcarbyne 1 reacts with acetonitrile to afford the first metallapyridinium complex 2 in high yield (see scheme). Deprotonation of 2 gives the first osmapyridine compound 3. Treatment of 3 with HBF4 can regenerate 2 in almost quantitative yield." @default.
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- W2155309451 date "2009-07-08" @default.
- W2155309451 modified "2023-10-17" @default.
- W2155309451 title "Osmapyridine and Osmapyridinium from a Formal [4+2] Cycloaddition Reaction" @default.
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- W2155309451 doi "https://doi.org/10.1002/anie.200900998" @default.
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