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• W2155361906 endingPage "13094" @default.
• W2155361906 startingPage "13082" @default.
• W2155361906 abstract "Abstract A new, versatile chloride‐anion‐templating synthetic pathway is exploited for the preparation of a series of eight new [2]rotaxane host molecules, including the first sulfonamide interlocked system. 1 H NMR spectroscopic titration investigations demonstrate the rotaxanes’ capability to selectively recognise the chloride anion in competitive aqueous solvent media. The interlocked host’s halide binding affinity can be further enhanced and tuned through the attachment of electron‐withdrawing substituents and by increasing its positive charge. A dicationic rotaxane selectively binds chloride in 35 % water, wherein no evidence of oxoanion binding is observed. NMR spectroscopy, X‐ray structural analysis and computational molecular dynamics simulations are used to account for rotaxane formation yields, anion binding strengths and selectivity trends." @default.
• W2155361906 created "2016-06-24" @default.
• W2155361906 creator A5009824212 @default.
• W2155361906 creator A5010873983 @default.
• W2155361906 creator A5042115358 @default.
• W2155361906 creator A5043326655 @default.
• W2155361906 creator A5045032736 @default.
• W2155361906 creator A5055761106 @default.
• W2155361906 creator A5070071494 @default.
• W2155361906 creator A5087293411 @default.
• W2155361906 date "2010-10-28" @default.
• W2155361906 modified "2023-10-18" @default.
• W2155361906 title "Rotaxanes Capable of Recognising Chloride in Aqueous Media" @default.
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