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- W2155364461 abstract "The reaction behavior of functionalized oximes such as 1 is decisively influenced by the position of the N-hydroxyl group. Thus the (Z)-isomer reacts in the presence of diisobutylaluminum hydride to give the azepane 2, while the (E)-isomer gives the perhydroquinoline 3. Apparently, during the formation of 2 a Beckmann rearrangement first takes place with ring expansion, whereas in the case of 3 the oxime N atom is inserted directly into the ring that is being formed." @default.
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- W2155364461 date "1991-06-01" @default.
- W2155364461 modified "2023-10-16" @default.
- W2155364461 title "Synthesis of Heterocycles by Tandem Reactions: Beckmann Rearrangements/Allylsilane Cyclizations" @default.
- W2155364461 doi "https://doi.org/10.1002/anie.199106871" @default.
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