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• W2155388947 endingPage "6081" @default.
• W2155388947 startingPage "6073" @default.
• W2155388947 abstract "A chromium complex [2-(NHCH2PPh2)C5H4N]CrCl3·THF2 (1) of the ligand PyNHCH2PPh2 has been synthesized, characterized, and examined for its catalytic behavior toward ethylene oligomerization. When complex 1 was treated with (i-Bu)3Al, an unprecedented divalent polyhydride chromium cluster μ,κ1,κ2,κ3-N,N,P-{[2-(NCH2PPh2)C5H4N]Cr(μ-H)}4[(μ-Cl)Cr(μ-Cl)Al(i-Bu)2Cl]2 (2) was obtained. The complex contains a Cr4H4 core, which is expected to be diamagnetic, and which remains coordinated to two additional divalent high-spin Cr atoms via bridging interactions. Two aluminate residues remain bonded to the peripheral chromium atoms. The structure, magnetism, and electronic configuration are herein discussed." @default.
• W2155388947 created "2016-06-24" @default.
• W2155388947 creator A5005231521 @default.
• W2155388947 creator A5025521469 @default.
• W2155388947 creator A5026611636 @default.
• W2155388947 creator A5034555955 @default.
• W2155388947 creator A5063225492 @default.
• W2155388947 creator A5066675504 @default.
• W2155388947 date "2014-05-29" @default.
• W2155388947 modified "2023-09-26" @default.
• W2155388947 title "Isolation of a Hexanuclear Chromium Cluster with a Tetrahedral Hydridic Core and Its Catalytic Behavior for Ethylene Oligomerization" @default.
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