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• W2155453587 abstract "A single, convenient reaction protocol and the same set of readily available starting materials suffice for the modular synthesis of all possible polypropionate diastereomers. This general method for the diastereoselective synthesis of syn, anti, and methyl ketone aldol adducts utilizes a powerful MgII -mediated, hydroxy-directed nitrile oxide cycloaddition. The free hydroxy group provides an ideal synthetic handle enabling the rapid assembly of complex polyketide structures. TBS=tBuMe2 Si." @default.
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• W2155453587 date "2001-06-01" @default.
• W2155453587 modified "2023-10-17" @default.
• W2155453587 title "A General Solution to the Modular Synthesis of Polyketide Building Blocks by Kanemasa Hydroxy-Directed Nitrile Oxide Cycloadditions This work was supported by the ETH-Zürich, Hoffmann-LaRoche, Merck, and Novartis. J.W.B. thanks the National Science Foundation (USA) for a predoctoral fellowship. We are grateful to Boehringer-Ingelheim for a generous gift of (R)-3-buten-2-ol. " @default.
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