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• W2155490944 startingPage "11514" @default.
• W2155490944 abstract "Easy to cope with: Experimental evidence was found to support an enzymatic [3,3]-sigmatropic rearrangement catalyzed by dimethylallyltryptophan (DMAT) synthase (see scheme). A bio-inspired system showed the feasibility of Cope rearrangement to the C-4 position of the indole nucleus. The tricyclic benzo[cd]indole core of welwitindolinones and dragmacidin E was synthesized using this transformation." @default.
• W2155490944 created "2016-06-24" @default.
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• W2155490944 date "2012-10-10" @default.
• W2155490944 modified "2023-10-18" @default.
• W2155490944 title "Mimicking Dimethylallyltryptophan Synthase: Experimental Evidence for a Biosynthetic Cope Rearrangement Process" @default.
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• W2155490944 doi "https://doi.org/10.1002/anie.201203586" @default.
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