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- W2155581714 abstract "The previous concepts of MO theories in terms of crystal field and ligand field theory have been found confusing in careful contrast to practical observation and findings of molecular oxygenation. The present perennial electron mobility and consequent flood of mobile electrons has been found to explain these observations, accounting for the quantum transition state (QTS), ensuring right randomization. The processes of conformation and isomerization have been shown possible over the mobile bed of electrons under controlled energy conditions tamed by finer T-t (time and temperature) adjustments. The process of NO2 isomerization has hinted to O2 also as isomerizing agent in QTS of oxygenation. Ständige Elektronenmobilität für die ideale molekulare Oxidation; Isomerisierung unter kontrollierten Bedingungen Die früheren Vorstellungen der MO-Theorien in bezug auf Kristallfeld und Liganden-Feldtheorie sind irritierend, und sie stehen nicht im Einklang mit praktischen Beobachtungen bei der molekularen Oxidation. Das gegenwärtige Konzept der ständigen Elektronenmobilität erklärt die obigen Beobachtungen unter Berücksichtigung des Quantenübergangsstadiums. Die Vorgänge der Konformation und Isomerisierung sind möglich über die mobilen Elektronen unter kontrollierten Energie-bedingungen. Es wird angedeutet, daß bei der Isomerisierung durch NO2 auch der Sauerstoff als Isomerisierungsmittel fungiert." @default.
- W2155581714 created "2016-06-24" @default.
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- W2155581714 date "1973-01-01" @default.
- W2155581714 modified "2023-10-17" @default.
- W2155581714 title "Perennial Electron Mobility for Molecular Ideal Oxygenation, Conformation and Isomerization under Controlled Conditions" @default.
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- W2155581714 doi "https://doi.org/10.1002/lipi.19730750407" @default.
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