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- W2155609815 abstract "Abstract Single crystals of CeAu 4 Si 2 and CeAu 2 Si 2 have been grown out of ternary fluxes rich in Au, and the former, also by sintering the stoichiometric composition at 750 °C. The single-crystal X-ray refinement result for CeAu 4 Si 2 is orthorhombic, Cmmm (No. 65, Z =2), different from a tetragonal result found from an X-ray powder diffraction refinement [H. Nakashima, et al., J. Alloys Compds. 424 (2006) 7]. For CeAu 2 Si 2 , this is the first report of the stoichiometric crystalline phase, in the known tetragonal I 4/ mmm structure. The anisotropic field- and temperature-dependent magnetizations, as well as specific heat and resistivity data are compared. Although both compounds have related structural packing, they present unique magnetic features. CeAu 2 Si 2 is a typical antiferromagnet with T N =8.8(1) K and CeAu 4 Si 2 features a ferromagnetic component below T c =3.3(1) K. Both phases have effective moments close in value to that of free Ce 3+ ." @default.
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- W2155609815 date "2008-06-17" @default.
- W2155609815 modified "2023-10-02" @default.
- W2155609815 title "ChemInform Abstract: Crystal Structures and Magnetic Properties of CeAu4Si2and CeAu2Si2." @default.
- W2155609815 cites W2082249027 @default.
- W2155609815 doi "https://doi.org/10.1002/chin.200825005" @default.
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