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• W2155654405 abstract "A general route to enantioenriched tert-butyl 3,3-diarylpropanoates is presented. These useful building blocks are prepared via an asymmetric rhodium-catalyzed conjugate addition of arylboronic acids to unsaturated tert-butyl esters in the presence of chiral dienes as ligands. The addition of both electron-poor and electron-rich boronic acids proceeds smoothly with various enoates in 63−90% yield with high enantioselectivites (89−94% ee)." @default.
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• W2155654405 date "2005-07-14" @default.
• W2155654405 modified "2023-10-02" @default.
• W2155654405 title "Catalytic Asymmetric Synthesis with Rh−Diene Complexes: 1,4-Addition of Arylboronic Acids to Unsaturated Esters" @default.
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• W2155654405 doi "https://doi.org/10.1021/ol051533l" @default.
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