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- W2155706623 abstract "Among established methods for transforming Si-H bonds, carbonyl hydrosilylation and heterodehydrogenative coupling with alcohols catalysed by B(C6F5)3 are shown to provide exceptionally clean routes to the derivatisation of tetra-substituted disilanes such as [Ph2SiH]2, giving no products resulting from Si-Si bond cleavage. Even higher activity is observed for the borane-catalysed dehydrogenative coupling of silanes with alkyl- and arylthiols, the first examples of such Si-S bond formation in the absence of a transition metal catalyst. Clean, quantitative syntheses of a range of thiosilanes are reported, and the lability of the Si-S linkage toward subsequent alcoholysis is investigated. The crystal structure of 2,3-disila-2,2,3,3-tetramethyl-1,4-benzodioxane is presented." @default.
- W2155706623 created "2016-06-24" @default.
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- W2155706623 date "2008-01-01" @default.
- W2155706623 modified "2023-10-14" @default.
- W2155706623 title "Toward selective functionalisation of oligosilanes: borane-catalysed dehydrogenative coupling of silanes with thiols" @default.
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- W2155706623 doi "https://doi.org/10.1039/b806270f" @default.
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