FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2155727884> ?p ?o ?g. }

• W2155727884 endingPage "16625" @default.
• W2155727884 startingPage "16615" @default.
• W2155727884 abstract "On the basis of mass spectrometric experiments and quantum chemical calculations, including detailed kinetic and dynamics calculations, we report the unimolecular dissociation of an isolated glycolate anion. The dominating processes are: loss of formaldehyde; loss of carbon monoxide; loss of carbon dioxide; and loss of a hydrogen molecule, with the latter having the lowest energetic threshold. At higher energies, CO loss is the dominating reaction. The loss of CO may be followed by a second CO loss, leading to the H−H2O complex in close mechanistic relationship to the Nibbering reaction. The results provide valuable insights into possible mechanisms for interstellar and prebiotic formation of glycolate via the reverse of the unimolecular dissociation reactions. We propose that the addition of the complex of OH− and CO to CH2O is the most feasible route to gas phase synthesis of glycolate, since all species are abundant in interstellar space." @default.
• W2155727884 created "2016-06-24" @default.
• W2155727884 creator A5029387173 @default.
• W2155727884 creator A5042979239 @default.
• W2155727884 creator A5065439849 @default.
• W2155727884 creator A5078995834 @default.
• W2155727884 creator A5084410882 @default.
• W2155727884 date "2013-01-01" @default.
• W2155727884 modified "2023-10-14" @default.
• W2155727884 title "The dissociation of glycolate—astrochemical and prebiotic relevance" @default.
• W2155727884 cites W1842905390 @default.
• W2155727884 cites W1969349353 @default.
• W2155727884 cites W1970919857 @default.
• W2155727884 cites W1981644447 @default.
• W2155727884 cites W1991662337 @default.
• W2155727884 cites W1997128703 @default.
• W2155727884 cites W2002782616 @default.
• W2155727884 cites W2006329860 @default.
• W2155727884 cites W2006567794 @default.
• W2155727884 cites W2018937156 @default.
• W2155727884 cites W2019320262 @default.
• W2155727884 cites W2021724334 @default.
• W2155727884 cites W2024621713 @default.
• W2155727884 cites W2024662702 @default.
• W2155727884 cites W2027838421 @default.
• W2155727884 cites W2029512101 @default.
• W2155727884 cites W2029618976 @default.
• W2155727884 cites W2031140687 @default.
• W2155727884 cites W2041548070 @default.
• W2155727884 cites W2043707669 @default.
• W2155727884 cites W2046364445 @default.
• W2155727884 cites W2050275535 @default.
• W2155727884 cites W2051817968 @default.
• W2155727884 cites W2053964761 @default.
• W2155727884 cites W2057787908 @default.
• W2155727884 cites W2059085274 @default.
• W2155727884 cites W2064527270 @default.
• W2155727884 cites W2064595858 @default.
• W2155727884 cites W2065882166 @default.
• W2155727884 cites W2067204559 @default.
• W2155727884 cites W2069006374 @default.
• W2155727884 cites W2070220353 @default.
• W2155727884 cites W2070927660 @default.
• W2155727884 cites W2073911681 @default.
• W2155727884 cites W2075711588 @default.
• W2155727884 cites W2076118313 @default.
• W2155727884 cites W2078750907 @default.
• W2155727884 cites W2080922008 @default.
• W2155727884 cites W2082608963 @default.
• W2155727884 cites W2085902490 @default.
• W2155727884 cites W2090537574 @default.
• W2155727884 cites W2091825943 @default.
• W2155727884 cites W2094769869 @default.
• W2155727884 cites W2106689890 @default.
• W2155727884 cites W2132069637 @default.
• W2155727884 cites W2136949385 @default.
• W2155727884 cites W2169678694 @default.
• W2155727884 cites W3100252042 @default.
• W2155727884 cites W3102500414 @default.
• W2155727884 cites W4237260802 @default.
• W2155727884 doi "https://doi.org/10.1039/c3cp51638e" @default.
• W2155727884 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23959262" @default.
• W2155727884 hasPublicationYear "2013" @default.
• W2155727884 type Work @default.
• W2155727884 sameAs 2155727884 @default.
• W2155727884 citedByCount "12" @default.
• W2155727884 countsByYear W21557278842014 @default.
• W2155727884 countsByYear W21557278842015 @default.
• W2155727884 countsByYear W21557278842016 @default.
• W2155727884 countsByYear W21557278842017 @default.
• W2155727884 countsByYear W21557278842018 @default.
• W2155727884 countsByYear W21557278842023 @default.
• W2155727884 crossrefType "journal-article" @default.
• W2155727884 hasAuthorship W2155727884A5029387173 @default.
• W2155727884 hasAuthorship W2155727884A5042979239 @default.
• W2155727884 hasAuthorship W2155727884A5065439849 @default.
• W2155727884 hasAuthorship W2155727884A5078995834 @default.
• W2155727884 hasAuthorship W2155727884A5084410882 @default.
• W2155727884 hasBestOaLocation W21557278841 @default.
• W2155727884 hasConcept C102931765 @default.
• W2155727884 hasConcept C121332964 @default.
• W2155727884 hasConcept C147597530 @default.
• W2155727884 hasConcept C147789679 @default.
• W2155727884 hasConcept C159467904 @default.
• W2155727884 hasConcept C161790260 @default.
• W2155727884 hasConcept C177801218 @default.
• W2155727884 hasConcept C178790620 @default.
• W2155727884 hasConcept C180920033 @default.
• W2155727884 hasConcept C185592680 @default.
• W2155727884 hasConcept C196939603 @default.
• W2155727884 hasConcept C2775930285 @default.
• W2155727884 hasConcept C32909587 @default.
• W2155727884 hasConcept C44870925 @default.
• W2155727884 hasConcept C512735826 @default.
• W2155727884 hasConcept C512968161 @default.
• W2155727884 hasConcept C75473681 @default.
• W2155727884 hasConcept C87355193 @default.
• W2155727884 hasConcept C98444146 @default.

• next