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- W2155754906 abstract "Abstract Two approaches are described for the preparation of 2‐(1′,3′‐dioxoalkyl)‐substituted 1‐hydroxyanthraquinones 10a − d and 20a − c , which were cyclized in a biomimetic‐type reaction to the anthra[1,2‐ b ]pyran skeletons 11a − d and 21a − c of the heydamycin‐ or pluramycin‐type antibiotics. Cleavage of the methyl ethers afforded the natural product premithramycinone H ( 2 ). The simple derivative 11b showed inhibition of the A431 cell line in µmolar concentrations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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- W2155754906 date "2003-12-11" @default.
- W2155754906 modified "2023-10-03" @default.
- W2155754906 title "Total Synthesis of Premithramycinone H and Related Anthrapyran Antibiotics" @default.
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- W2155754906 doi "https://doi.org/10.1002/ejoc.200300451" @default.
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