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• W2156021137 abstract "Reactivity along two channels is shown by the HOFeVO species responsible for Fe(tpa)-catalyzed olefin oxidation (tpa=tris(2-pyridylmethyl)amine). Attack of the oxo ligand on an olefinic carbon atom yields epoxide and attack of the hydroxo ligand affords cis-diol (see scheme). Hybrid density functional theory now demonstrates that the two processes have comparable activation energies." @default.
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• W2156021137 date "2005-05-03" @default.
• W2156021137 modified "2023-10-17" @default.
• W2156021137 title "Two Faces of a Biomimetic Non-Heme HOFeVO Oxidant: Olefin Epoxidation versuscis-Dihydroxylation" @default.
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• W2156021137 doi "https://doi.org/10.1002/anie.200463072" @default.
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