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- W2156156776 abstract "A convenient and useful esterification was realized, and this reaction proceeded without a dehydrating reagent or water removal equipment. A series of ortho-hydroxyphenyl carboxylic acids and benzoic acids were transformed to their corresponding methyl esters under CAN/CH3OH reaction conditions. Whereas in an aprotic solvent, acetonitrile, sp3-C tethered ortho-hydroxyphenyl carboxylic acids undergo simultaneous o,p-dinitration and intramolecular esterification reactions in good yields. Also, 2-((1 E)-2-nitrovinyl)-4-nitro-phenol (3e) showed selective cytotoxicities toward MCF-7, HEP G2, and HEP 3B cell lines with IC50 values of 23.50, 7.33, and 7.59 ug/mL, respectively." @default.
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- W2156156776 date "2005-02-01" @default.
- W2156156776 modified "2023-10-18" @default.
- W2156156776 title "Esterification-nitration ofOrtho-hydroxyphenyl Carboxylic Acids and Benzoic Acids with Cerium(IV) Ammonium Nitrate (CAN)" @default.
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- W2156156776 doi "https://doi.org/10.1002/jccs.200500027" @default.
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