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- W2156197578 abstract "Experimental results of the hydrostatic pressure influence on Mössbauer spectrum parameters are obtained over the pressure range including the area of structural phase transition. A linear increase of the Mössbauer effect probability (recoilless fraction) is accompanied by a linear decrease of the electron density at tin nuclei within the pressure range foregoing the phase transition. The electric resistance and the recoilless fraction of the new phase of Mg2Sn are lower, but the electron density at tin nuclei is greater than the initial phase ones. Hydrostatic conditions allow to fix clearly the diphasic transition area and to determine the influence of the pressure on the Mössbauer line position and on the recoilless fraction of the high pressure phase. The phase transition heat Q = 415 cal mol−1 is calculated using recoilless fractions of the high and low pressure phases at 25 kbar. The present results are qualitatively and quantitatively different from the results, obtained at nonhydrostatic conditions. [Russian Text Ignored]." @default.
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- W2156197578 date "1979-06-16" @default.
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- W2156197578 title "Mössbauer study of phase transitions under high hydrostatic pressures. I. The phase transition of Mg2Sn" @default.
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- W2156197578 doi "https://doi.org/10.1002/pssa.2210530209" @default.
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