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- W2156411805 abstract "Quaternary alloyed nanocrystals (NCs) composed of earth abundant, environment friendly elements are of interest for energy-harvesting applications. These complex NCs are useful as catalysts for the degradation of multiple refractory organic pollutants as well as nitro-organic reduction at a rapid rate. Here, a remarkably fast (∼30 s) and facile synthesis of crystalline quaternary chalcopyrite copper-zinc-iron-sulfide (CZIS) NCs is reported. These NCs show excellent catalytic properties by degrading a number of refractory organic dyes and converting nitro-compounds at a rapid rate. The valence and conduction band information of the newly designed NCs are extracted using scanning tunneling spectroscopy and ultraviolet photoelectron spectroscopy, which reveal energy levels suitable for performing redox chemistry by generating reactive radicals establishing NCs as efficient catalyst with multiple uses. Rapid synthesis of high quality phase-controlled CZIS NCs with robust catalytic activities could be useful for organic waste treatment." @default.
- W2156411805 created "2016-06-24" @default.
- W2156411805 creator A5029614086 @default.
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- W2156411805 creator A5052254061 @default.
- W2156411805 creator A5052791219 @default.
- W2156411805 creator A5061469016 @default.
- W2156411805 date "2014-12-15" @default.
- W2156411805 modified "2023-10-03" @default.
- W2156411805 title "Mechanism of Versatile Catalytic Activities of Quaternary CuZnFeS Nanocrystals Designed by a Rapid Synthesis Route" @default.
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- W2156411805 doi "https://doi.org/10.1002/smll.201402837" @default.
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