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• W2156516616 abstract "Sulfenate anions are known to act as highly reactive species in the organic arena. Now they premiere as organocatalysts. Proof of concept is offered by the sulfoxide/sulfenate-catalyzed (1–10 mol %) coupling of benzyl halides in the presence of base to generate trans-stilbenes in good to excellent yields (up to 99 %). Mechanistic studies support the intermediacy of sulfenate anions, and the deprotonated sulfoxide was determined to be the resting state of the catalyst." @default.
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• W2156516616 date "2014-08-11" @default.
• W2156516616 modified "2023-09-23" @default.
• W2156516616 title "A New Class of Organocatalysts: Sulfenate Anions" @default.
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• W2156516616 doi "https://doi.org/10.1002/anie.201405996" @default.
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