Matches in SemOpenAlex for { <https://semopenalex.org/work/W2156574707> ?p ?o ?g. }
- W2156574707 endingPage "2508" @default.
- W2156574707 startingPage "2498" @default.
- W2156574707 abstract "Abstract Traditionally the fluorous phase is generated with perfluorinated alkyl groups that are usually perfluorooctyl or longer and are bioaccummulative and biopersistent and therefore, are considered environmentally unfriendly. Here we report a new concept for the construction of the fluorous phase. This concept is based on the amplification of the fluorous effect with the help of dendritic architectures containing very short semifluorinated groups on their periphery. This new concept was demonstrated by the convergent synthesis of the first and second generation AB 3 and AB 2 benzyl ether dendrons functionalized on their periphery via catalytic nucleophilic addition of their phenolates to perfluoropropyl vinyl ether. The resulting dendrons are liquids. Their fluorous phase affinity was analyzed and demonstrated that the dendritic architecture amplifies the fluorous phase at a specific generation by the number of functional groups on the dendron periphery, and at different generations by increasing their generation number. Therefore, this concept is very efficient for the design and synthesis of new fluorous materials. In addition, by contrast with dendrons containing perfluoroalkyl groups on their periphery, the current dendrons mediate the disassembly of their parent building blocks but do not mediate the self‐assembly in a supramolecular architecture. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2498–2508, 2010" @default.
- W2156574707 created "2016-06-24" @default.
- W2156574707 creator A5023792818 @default.
- W2156574707 creator A5035994558 @default.
- W2156574707 creator A5055867175 @default.
- W2156574707 creator A5084942404 @default.
- W2156574707 date "2010-04-26" @default.
- W2156574707 modified "2023-10-18" @default.
- W2156574707 title "Disassembly via an environmentally friendly and efficient fluorous phase constructed with dendritic architectures" @default.
- W2156574707 cites W1967130592 @default.
- W2156574707 cites W1967792315 @default.
- W2156574707 cites W1968148714 @default.
- W2156574707 cites W196968297 @default.
- W2156574707 cites W1971039731 @default.
- W2156574707 cites W1972137642 @default.
- W2156574707 cites W1974738767 @default.
- W2156574707 cites W1976149404 @default.
- W2156574707 cites W1976743478 @default.
- W2156574707 cites W1977219469 @default.
- W2156574707 cites W1984781743 @default.
- W2156574707 cites W1986850468 @default.
- W2156574707 cites W1987670755 @default.
- W2156574707 cites W1991890256 @default.
- W2156574707 cites W1992895908 @default.
- W2156574707 cites W1993243262 @default.
- W2156574707 cites W1998584594 @default.
- W2156574707 cites W2001477185 @default.
- W2156574707 cites W2003110973 @default.
- W2156574707 cites W2004838689 @default.
- W2156574707 cites W2008260159 @default.
- W2156574707 cites W2008539881 @default.
- W2156574707 cites W2008657337 @default.
- W2156574707 cites W2012863800 @default.
- W2156574707 cites W2014442771 @default.
- W2156574707 cites W2015006965 @default.
- W2156574707 cites W2016063423 @default.
- W2156574707 cites W2018008206 @default.
- W2156574707 cites W2018366267 @default.
- W2156574707 cites W2018525038 @default.
- W2156574707 cites W2019932200 @default.
- W2156574707 cites W2020120897 @default.
- W2156574707 cites W2021396019 @default.
- W2156574707 cites W2026144305 @default.
- W2156574707 cites W2028709150 @default.
- W2156574707 cites W2033472307 @default.
- W2156574707 cites W2035224982 @default.
- W2156574707 cites W2037879206 @default.
- W2156574707 cites W2039118776 @default.
- W2156574707 cites W2043096625 @default.
- W2156574707 cites W2048111541 @default.
- W2156574707 cites W2050860478 @default.
- W2156574707 cites W2054962478 @default.
- W2156574707 cites W2056028372 @default.
- W2156574707 cites W2064865136 @default.
- W2156574707 cites W2065777050 @default.
- W2156574707 cites W2070018504 @default.
- W2156574707 cites W2073623673 @default.
- W2156574707 cites W2077756249 @default.
- W2156574707 cites W2077976836 @default.
- W2156574707 cites W2078154140 @default.
- W2156574707 cites W2080486546 @default.
- W2156574707 cites W2080988955 @default.
- W2156574707 cites W2083248984 @default.
- W2156574707 cites W2085441783 @default.
- W2156574707 cites W2085724356 @default.
- W2156574707 cites W2087761815 @default.
- W2156574707 cites W2090651436 @default.
- W2156574707 cites W2091835805 @default.
- W2156574707 cites W2093981213 @default.
- W2156574707 cites W2101407709 @default.
- W2156574707 cites W2101506599 @default.
- W2156574707 cites W2105791810 @default.
- W2156574707 cites W2123155667 @default.
- W2156574707 cites W2133025340 @default.
- W2156574707 cites W2134480347 @default.
- W2156574707 cites W2134602939 @default.
- W2156574707 cites W2136727826 @default.
- W2156574707 cites W2140051962 @default.
- W2156574707 cites W2145165968 @default.
- W2156574707 cites W2148912121 @default.
- W2156574707 cites W2154493274 @default.
- W2156574707 cites W2154678311 @default.
- W2156574707 cites W2155744992 @default.
- W2156574707 cites W2161008403 @default.
- W2156574707 cites W2170458620 @default.
- W2156574707 cites W2172052812 @default.
- W2156574707 cites W2495287617 @default.
- W2156574707 cites W2950449118 @default.
- W2156574707 cites W2950748706 @default.
- W2156574707 cites W2952784256 @default.
- W2156574707 cites W4237832220 @default.
- W2156574707 cites W4246275874 @default.
- W2156574707 cites W4253660310 @default.
- W2156574707 doi "https://doi.org/10.1002/pola.24046" @default.
- W2156574707 hasPublicationYear "2010" @default.
- W2156574707 type Work @default.
- W2156574707 sameAs 2156574707 @default.
- W2156574707 citedByCount "29" @default.