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- W2156576265 abstract "Abstract We report herein the fabrication of visible‐light responsive n‐type PbTiO 3 by a combustion method and p‐type Cu‐doped PbTiO 3 by an impregnation method to improve hydrogen production activity. Copper was doped into the PbTiO 3 lattice up to 1 wt %; any further increase in the loading resulted in the formation of CuO on the surface of the sample. Photoluminescence confirmed that 1 wt % Cu‐doped PbTiO 3 effectively suppressed the defects in PbTiO 3 , which helped to reduce the recombination rate of the photoinduced charge carriers. The prepared PbTiO 3 photocatalyst behaves as an n‐type semiconductor, whereas 1 wt % Cu‐doped PbTiO 3 behaves as a p‐type semiconductor. The photocatalytic hydrogen production activity of PbTiO 3 increased with increasing Cu content up to 1 wt % and thereafter decreased upon further loading. The 1 wt % Cu‐doped PbTiO 3 sample showed higher activity for hydrogen liberation than pristine PbTiO 3 (2.5 times) and all of the other CuO‐loaded samples . The energy conversion efficiency of 1 wt % Cu‐doped PbTiO 3 was 5.95 % for hydrogen production under visible‐light irradiation. The enhanced hydrogen production activity of Cu‐doped PbTiO 3 was discussed on the basis of optimum copper doping, photoluminescence intensity, and their band‐edge positions. However, the higher activity of CuO‐loaded (>1 wt %) PbTiO 3 relative to that of neat PbTiO 3 is perhaps a result of the extensive light absorption properties of the CuO nanoparticles, which help to generate more electron–hole pairs on the surface." @default.
- W2156576265 created "2016-06-24" @default.
- W2156576265 creator A5052358078 @default.
- W2156576265 creator A5085342643 @default.
- W2156576265 date "2013-11-11" @default.
- W2156576265 modified "2023-10-18" @default.
- W2156576265 title "Fabrication, Characterization, and Photoelectrochemical Properties of Cu-Doped PbTiO<sub>3</sub>and Its Hydrogen Production Activity" @default.
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- W2156576265 doi "https://doi.org/10.1002/cctc.201300462" @default.
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