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• W2156830879 abstract "Treatment of dimethyl 4-(phenylsulfonyl)-4,5-hexadiene-1,1-dicarboxylate with potassium tert-butoxide in tert-butanol at room temperature effected successive endo-mode ring closure at the sp-hybridized carbon center and demethoxycarbonylation of the resulting malonate derivative leading to the exclusive formation of methyl 2-methyl-3-(phenylsulfonyl)-1-cyclopentenecarboxylate. An additional seven allenyl sulfones having a 1,3-dicarbonyl functionality gave the corresponding cyclopentene or cyclohexene derivatives in high yields." @default.
• W2156830879 created "2016-06-24" @default.
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• W2156830879 date "2003-02-01" @default.
• W2156830879 modified "2023-10-18" @default.
• W2156830879 title "A new entry to carbocycles: synthesis of cyclopentene and cyclohexene derivatives through endo-mode ring closure of allenyl sulfones" @default.
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• W2156830879 doi "https://doi.org/10.1016/s0040-4039(03)00067-4" @default.
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