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- W2156922387 abstract "All five: The first total synthesis of the C2-symmetric indole alkaloid 1 involved a late-stage thallium(III) acetate-mediated intermolecular oxidative coupling to construct the C9C9′ bond with complete regio- and stereocontrol. The formation of a single atropodiastereomer in this critical step arises from internal asymmetric induction. The first total synthesis of four other monomeric sarpagine indole alkaloids is also described." @default.
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- W2156922387 date "2012-10-16" @default.
- W2156922387 modified "2023-10-18" @default.
- W2156922387 title "Nature-Inspired Stereospecific Total Synthesis of<i>P</i>-(+)-Dispegatrine and Four Other Monomeric<i>Sarpagine</i>Indole Alkaloids" @default.
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- W2156922387 doi "https://doi.org/10.1002/anie.201206015" @default.
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