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- W2157018859 abstract "A calorimetric approach has been employed to study undercooling of metals and alloys using a high temperature differential scanning instrument. The samples are kept under alumina powder, the entire cell is evacuated several times, and heated or cooled under flowing helium. Undercooling can exceed 200 K (as found for pure Ni and Fe). Ni-B, Fe-B, Pd-Si alloys around eutectic compositions, as well as several multicomponent glass-forming alloys, were also significantly undercooled and the solidification of metastable phases was detected. The heat of fusion at the eutectic temperature and the heats of solidification in the undercooling regime have been determined. The thermal data are compatible with the existence of a substantial excess specific heat of the melt for glass-forming alloys whereas the specific heat difference between liquid and crystal phases is nil for pure metals. The undercooling could be extended further when the samples were previously fluxed in molten B 2 O 3 or boro-silicates." @default.
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- W2157018859 date "2000-01-01" @default.
- W2157018859 modified "2023-09-23" @default.
- W2157018859 title "Calorimetry of Undercooled Metals and Alloys" @default.
- W2157018859 doi "https://doi.org/10.4028/www.scientific.net/msf.329-330.507" @default.
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